I am starting to learn VSTFS 2010 with the new VS2010 and so far it looks pretty good.
I am still searching for good documentations or books to help create a good strategy. I found some documentation at MSDN but was hard to put together for printing so I started to compile some topics in a single MS Word document which is easy to print or read.
Here is my compiled document
and here is the original MSND link
I will try to keep the topics updated. Enjoy!